Grooved Electrodes May Improve Performance Of Proton

LOS ALAMOS, New Mexico – Proton-exchange membrane fuel cells are a promising energy solution for reducing carbon emissions in the transport sector. As suggested by their name, these cells contain a proton-conducting membrane based on polymer materials that serves as an electrolyte.

While PEMFCs could have notable advantages, their cost, durability and the availability of the fuel required to operate them will need to improve before they can be implemented on a large-scale.

Researchers at Los Alamos National Laboratory recently developed new electrodes that could significantly improve the performance and durability of PEMFCs. These electrodes, introduced in Nature Energy, have a characteristic grooved conformation that can facilitate the transport of both oxygen and protons in the fuel cells.

“We knew that the performance of conventional electrodes was limited by transport of species such as oxygen and protons, and we were inspired by the historic work of our colleagues at LANL in the 1990s, who discovered how to combine a carbon-supported platinum catalyst with proton-conducting ionomer to achieve major performance improvements,” Jacob Spendelow, one of the researchers who carried out the study, told Tech Xplore.

“It’s a bit surprising that, 30 years later, state-of-the-art electrodes still use essentially the same structure. We thus set out to redesign the structure by using a rational design approach to expedite both oxygen and proton transport.”

The grooved electrodes designed by Spendelow and his colleagues have numerous microscale ridges, which essentially consist of a carbon-supported platinum catalyst separated by empty indentations. Due to their unique configuration, they can partition the transport of oxygen and protons into different parts of their structure.

“Conventional electrodes require mixed transport of oxygen and protons through all parts of the electrode, which requires some design compromises, since the proton-conducting ionomer obstructs transport of oxygen,” Spendelow explained. “In contrast, by separating the oxygen and proton transport, the grooved electrode design allows parts of the electrode (the grooves) to be optimized for oxygen transport, while other parts (the ridges) are optimized for proton transport. This ‘divide and conquer’ approach enables faster transport and higher performance.”

The researchers evaluated their grooved electrodes in a series of tests run at standard operating conditions for fuel cells. They found that their performance was up to 50% better than that of conventional electrodes, and that they could facilitate the transport of oxygen and improve the uniformity of chemical reactions. In addition, the grooved electrodes appeared to be more durable than their conventional counterparts, as their performance did not decline as much after a carbon corrosion test.

To read more, click on TechExplore

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